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【英文标准名称】:StandardTestMethodforDissolvedHexavalentChromiuminWaterbyIonChromatography
【原文标准名称】:用离子色谱法测定水中可溶六价铬的标准试验方法
【标准号】:ASTMD5257-2003
【标准状态】:现行
【国别】:
【发布日期】:2003
【实施或试行日期】:
【发布单位】:美国材料与试验协会(US-ASTM)
【起草单位】:D19.05
【标准类型】:(TestMethod)
【标准水平】:()
【中文主题词】:水;色谱法;含量测定;离子
【英文主题词】:analysis;hexavalentchromium;ionchromatography;wastewater;water
【摘要】:Hexavalentchromiumsaltsareusedextensivelyinthemetalfinishingandplatingindustries,intheleatherindustryasatanningagent,andinthemanufactureofpaints,dyes,explosives,andceramics.Trivalentchromiumsaltsareusedasmordantsintextiledying,intheceramicandglassindustry,andinphotography.Chromium,ineitheroxidationstate,maybepresentinwastewaterfromtheseindustriesandmayalsobedischargedfromchromate-treatedcoolingwaters.Hexavalentchromiumistoxictohumans,animals,andaquaticlife.Itcanproducelungtumorswheninhaledandreadilyinducesskinsensitization.Itisnotknownwhethercancerwillresultfromingestionofchromiuminanyofitsvalencestates.Ionchromatographyprovidesameansofseparatingthehexavalentchromiumfromotherspeciespresentinthesample,manyofwhichinterferewithotherdetectionmethods.Thecombinationofthisseparationwithasensitivecolorimetricdetectionmethodprovidesaselectiveandsensitiveanalyticalmethodforhexavalentchromiumwithminimalsamplepreparation.1.1Thistestmethodcoversproceduresforthedeterminationofdissolvedhexavalentchromiuminwastewater,surfacewater,anddrinkingwater.1.2Theprecisionandbiasofthistestmethodhasbeentestedinreagentwaterandindustrialwastewaterandhasbeenfoundsuitableovertherangeofapproximately1to1000956;g/L.Seefordetails.Higherlevelscanbedeterminedbyappropriatedilution.1.3Samplescontainingveryhighlevelsofanionicspecies(thatis,chloride,sulfate,etc.)maycausecolumnoverload.Samplescontaininghighlevelsofreducingspecies(thatis,sulfides,sulfites,etc.)maycausereductionofCr(VI)toCr(III).ThiscanbeminimizedbybufferingthesampletoapHof9to9.5,filteringit,storingitat4176;Candanalyzingitwithin24h.1.4ThevaluesstatedinSIunitsaretoberegardedasthestandard.1.5Thisstandarddoesnotpurporttoaddressallofthesafetyconcerns,ifany,associatedwithitsuse.Itistheresponsibilityoftheuserofthisstandardtoestablishappropriatesafetyandhealthpracticesanddeterminetheapplicabilityofregulatorylimitationspriortouse.
【中国标准分类号】:Z16
【国际标准分类号】:71_060_50
【页数】:7P.;A4
【正文语种】: